First, remember that gear is dropped depending on your current spec, not on which role you entered LFR as. If you queue as Tank, you're basically forced to stay Prot the entire run, while if you queue as DPS, you can respec at will. Sure, you'll do meager DPS, but who cares. And it's not entirely unheard of that tanks die during fights, so you'll be there to taunt the boss if that happens and save a raid wipe.
MSV first half. You want to be in Prot spec for the first and second boss, as Crit is near useless. For the third boss, the DPS items are nice, but once you have those, go Prot for the boots.
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MSV 1: Waist: Mastery/Dodge/2S Tank
MSV 1: Neck: Expertise/Dodge Tank
MSV 1: Feet: Mastery/Crit/1s DPS
MSV 2: Wrist: Dodge/Parry Tank
MSV 2: Head: Haste/Crit/2s DPS
MSV 2: Back: Expertise/Crit DPS
MSV 3: Feet: Mastery/Dodge/1s Tank
MSV 3: Wrist: Haste/Expertise DPS
MSV 3: Neck: Hit/Haste DPS
MSV second half. The first boss drops the only raiding shield in game, so go Prot until you have it. There are plenty of reasons to stay Prot on the second boss, but you probably want to go Retri on the third boss.
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MSV 4: Shldr: Hit/Parry/1s Tank
MSV 4: Shield: Dodge/Parry Tank
MSV 4: Chest: Haste/Mastery/2s DPS
MSV 5: 1H: Hit/Expertise Tank
MSV 5: Ring: Expertise/Dodge Tank
MSV 5: Trink: Mastery (Dodge) Tank
MSV 5: Hands: Hit/Haste/1s DPS
MSV 5: 2H: Expertise/Crit DPS
MSV 6: Chest: Expertise/Parry/2s Tank
MSV 6: Legs: Hit/Haste/2s DPS
MSV 6: Trink: Haste (Strength) DPS
HoF first half. The DPS back from the first boss is nice, but the waist is crap. There are two pretty decent Tank items, so you might want to go Prot. You probably want to go Retri on the second boss, but there's zero reason to go Retri on the third boss, due to Crit.
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HoF 1: Legs: Hit/Parry/2s Tank
HoF 1: Ring: Expertise/Parry Tank
HoF 1: Waist: Expertise/Crit/2s DPS
HoF 1: Back: Hit/Haste DPS
HoF 2: Shldr: Hit/Parry/1s Tank
HoF 2: Hands: Dodge/Parry/1s Tank
HoF 2: Waist: Haste/Mastery/2s DPS
HoF 2: Ring: Expertise/Haste DPS
HoF 3: Head: Dodge/Parry/2s Tank
HoF 3: Ring: Mastery/Dodge Tank
HoF 3: Chest: Hit/Crit/2s DPS
HoF 3: Neck: Mastery/Crit DPS
HoF second half. Tier pieces can drop no matter your spec, so they don't matter. The DPS boots from the first boss are nice, so go Retri until they drop. Go Prot for the other two bosses, as they drop no interesting DPS gear.
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HoF 4: Hands: Tier Tank/DPS
HoF 4: Back: Mastery/Dodge Tank
HoF 4: Feet: Hit/Haste DPS
HoF 5: Legs: Tier Tank/DPS
HoF 5: 1H: Hit/Mastery/1s Tank
HoF 5: Shldr: Crit/Mastery/1s DPS
HoF 6: Chest: Tier Tank/DPS
HoF 6: Legs: Dodge/Parry/2s Tank
ToES: Every single DPS item has Crit on it, so you might just as well queue up as Tank+DPS, and stay Prot the entire instance. The Hit/Mastery and Hit/Expertise items from the first boss, as well as the Strength trinket from the 3rd boss can drop regardless of spec.
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ToES 1: Wrist: Hit/Mastery Tank/DPS
ToES 1: Neck: Hit/Expertise Tank/DPS
ToES 1: Feet: Hit/Parry/1s Tank
ToES 1: Neck: Dodge/Parry Tank
ToES 2: Hands: Expertise/Parry/1s Tank
ToES 2: Waist: Expertise/Dodge/1s Tank
ToES 2: Back: Dodge/Parry Tank
ToES 2: Trink: Mastery (Dodge) Tank
ToES 2: Waist: Hit/Crit/1s DPS
ToES 2: Ring: Hit/Crit DPS
ToES 3: Trink: Strength (Haste) Tank/DPS
ToES 3: Shldr: Tier Tank/DPS
ToES 3: Chest: Mastery/Dodge/2s Tank
ToES 3: Waist: Expertise/Dodge/1s Tank
ToES 3: Waist: Hit/Crit/1s DPS
ToES 4: Head: Tier Tank/DPS
ToES 4: 1H: Hit/Mastery/Sha Tank
ToES 4: 2H: Mastery/Crit/Sha DPS
Note that the above advise assumes that you aren't in the slightest interested in upgrading your Retribution set. If you are, then check the list boss by boss. If a boss no longer provides any tanking upgrades, you should of course go DPS.